Ultraselective fluorescent sensing of Hg2+ through metal coordination-induced molecular aggregation

被引:151
作者
Che, Yanke [1 ]
Yang, Xiaomei [1 ]
Zang, Ling [1 ]
机构
[1] So Illinois Carbondale Univ, Dept Chem & Biochem, Carbondale, IL 62901 USA
基金
美国国家科学基金会;
关键词
D O I
10.1039/b719384j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new type of fluorescent sensor has been developed from a perylene based molecule, N, N'-dideoxythymidine-3,4,9,10-perylene-tetracarboxylic diimide (TT-PTCDI); the strong, highly selective binding between the thymine ligand ( T) and Hg(2+) ion enables efficient sensing of mercury ions based on a fluorescence quenching mechanism, which is primarily caused by metal-coordination induced molecular aggregation.
引用
收藏
页码:1413 / 1415
页数:3
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