Cyclization of N-butyl-4-pentenylaminyl: Implications for the cyclization of alkenylaminyl radicals

被引：25

作者：

Maxwell, BJ ^{[1
]}

Tsanaktsidis, J ^{[1
]}

机构：

[1] UNIV MELBOURNE, SCH CHEM, PARKVILLE, VIC 3052, AUSTRALIA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1996年 / 118卷 / 18期

关键词：

D O I：

10.1021/ja953720s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The utility of arenesulfenamides as aminyl radical precursors has been clearly demonstrated, The cyclization of N-butyl-4-pentenylaminyl is shown to be a slow and irreversible process that is accelerated significantly by small amounts of bis(tributyltin) oxide.

引用

页码：4276 / 4283

页数：8

共 53 条

[1]

ALLEN CFH, 1943, ORG SYNTH, V2, P580

[2] THE GENERATION OF AMINYL RADICALS FROM SULFENAMIDES [J].

BECKWITH, ALJ ;

MAXWELL, BJ ;

TSANAKTSIDIS, J .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1991, 44 (12) :1809-1812

[3] REGIO-SELECTIVITY AND STEREO-SELECTIVITY IN RADICAL REACTIONS [J].

BECKWITH, ALJ .

TETRAHEDRON, 1981, 37 (18) :3073-3100

[4]

BENNETT OF, 1974, ORG PREP P INT, V6, P287

[5] SYNTHESIS OF PYRROLIZIDINES USING AMINYL RADICALS GENERATED FROM SULFENAMIDE PRECURSORS [J].

BOWMAN, WR ;

CLARK, DN ;

MARMON, RJ .

TETRAHEDRON, 1994, 50 (04) :1295-1310

[6] SULFENAMIDES AS SYNTHETIC PRECURSORS OF AMINYL RADICALS [J].

BOWMAN, WR ;

CLARK, DN ;

MARMON, RJ .

TETRAHEDRON LETTERS, 1991, 32 (44) :6441-6444

[7] GENERATION OF AMINYL RADICALS USING SULFENAMIDES AS SYNTHETIC PRECURSORS [J].

BOWMAN, WR ;

CLARK, DN ;

MARMON, RJ .

TETRAHEDRON, 1994, 50 (04) :1275-1294

[8] RADICAL-ADDITION TO ALKENE METAL CATION COMPLEXES [J].

CLARK, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (24) :1774-1776

[9]

CRAINE L, 1989, CHEM REV, V89, P589

[10]

Curran D. P., 1991, COMPREHENSIVE ORGANI, V4, P715

← 1 2 3 4 5 6 →