Alkyl complexes of strontium and barium:: Synthesis and structural characterization of {(Me3Si)2(MeOMe2Si)C}2Sr(THF) and {(Me3Si)2(MeOMe2Si)C}2Ba(MeOCH2CH2OMe)

被引：35

作者：

Izod, K ^{[1
]}

Liddle, ST ^{[1
]}

Clegg, W ^{[1
]}

机构：

[1] Newcastle Univ, Sch Nat Sci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 25期

关键词：

D O I：

10.1021/ja0352404

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metathesis between either SrI2 or BaI2 and 2 equiv of {(Me3Si)2(MeOMe2Si)C}K in THF yields the novel heavier alkali metal dialkyls {(Me3Si)2(MeOMe2Si)C}2M(L) [M(L) = Sr(THF) (2), Ba(DME) (3) (DME = 1,2-dimethoxyethane)] after recrystallization. Copyright © 2003 American Chemical Society.

引用

页码：7534 / 7535

页数：2

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