Solid state electrochemical studies of mixed nickel-iron hexacyanoferrates with the help of abrasive stripping voltammetry

被引：111

作者：

Reddy, SJ ^{[1
]}

Dostal, A ^{[1
]}

Scholz, F ^{[1
]}

机构：

[1] HUMBOLDT UNIV BERLIN,INST CHEM,D-10115 BERLIN,GERMANY

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1996年 / 403卷 / 1-2期

关键词：

Ni-Fe hexacyanoferrates; cyclic voltammetry; solid state electrochemistry; X-ray diffraction;

D O I：

10.1016/0022-0728(95)04380-2

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The electrochemical behaviour of hexacyanoferrates containing different ratios of iron and nickel, attached mechanically to a graphite electrode, has been studied using cyclic voltammetric techniques. The results have shown that mixed crystals of Fe-Ni hexacyanoferrates are formed, with the nitrogen-coordinated iron being replaced by nickel in the lattice as the percentage of nickel increases, whilst retaining the lattice symmetry. X-ray diffraction data confirmed this theory.

引用

收藏

页码：209 / 212

页数：4

相关论文

共 14 条

[1] MORPHOLOGICAL VARIATION AT THE [NIFE(CN)6]2-/- DERIVATIZED NICKEL ELECTRODE - A TECHNIQUE FOR THE EVALUATION OF ALKALI CATION CONTAINING SOLUTIONS [J].

AMOS, LJ ;

DUGGAL, A ;

MIRSKY, EJ ;

RAGONESI, P ;

BOCARSLY, AB ;

FITZGERALDBOCARSLY, PA .

ANALYTICAL CHEMISTRY, 1988, 60 (03) :245-249

[2] MODIFIED ELECTRODES WITH MIXED METAL HEXACYANOFERRATES [J].

BHARATHI, S ;

JOSEPH, J ;

JEYAKUMAR, D ;

RAO, GP .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 319 (1-2) :341-345

[3] CRYSTAL-STRUCTURE OF PRUSSIAN BLUE - FE4[FE(CN)6]3.XH2O [J].

BUSER, HJ ;

SCHWARZENBACH, D ;

PETTER, W ;

LUDI, A .

INORGANIC CHEMISTRY, 1977, 16 (11) :2704-2710

[4] ELECTROCHEMISTRY OF CHROMIUM(II) HEXACYANOCHROMATE(III) AND ELECTROCHEMICALLY INDUCED ISOMERIZATION OF SOLID IRON(II) HEXACYANOCHROMATE(III) MECHANICALLY IMMOBILIZED ON THE SURFACE OF A GRAPHITE ELECTRODE [J].

DOSTAL, A ;

SCHRODER, U ;

SCHOLZ, F .

INORGANIC CHEMISTRY, 1995, 34 (07) :1711-1717

[5] ELECTROCHEMICAL STUDY OF MICROCRYSTALLINE SOLID PRUSSIAN BLUE PARTICLES MECHANICALLY ATTACHED TO GRAPHITE AND GOLD ELECTRODES - ELECTROCHEMICALLY INDUCED LATTICE RECONSTRUCTION [J].

DOSTAL, A ;

MEYER, B ;

SCHOLZ, F ;

SCHRODER, U ;

BOND, AM ;

MARKEN, F ;

SHAW, SJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (07) :2096-2103

[6] SOLID-STATE ELECTROCHEMISTRY - VOLTAMMETRIC MONITORING OF IONIC CONDUCTIVITIES IN MIXED-METAL HEXACYANOFERRATES [J].

KULESZA, PJ ;

GALUS, Z .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 269 (02) :455-460

[7] APPLICATION OF CHELATE-FORMING RESIN AND MODIFIED GLASSY-CARBON ELECTRODE FOR SELECTIVE DETERMINATION OF IRON(III) BY LIQUID-CHROMATOGRAPHY WITH ELECTROCHEMICAL DETECTION [J].

KULESZA, PJ ;

BRAJTER, K ;

DABEKZLOTORZYNSKA, E .

ANALYTICAL CHEMISTRY, 1987, 59 (23) :2776-2780

[8] ION SELECTIVITY IN NICKEL HEXACYANOFERRATE FILMS ON ELECTRODE SURFACES [J].

SCHNEEMEYER, LF ;

SPENGLER, SE ;

MURPHY, DW .

INORGANIC CHEMISTRY, 1985, 24 (19) :3044-3046

[9] IDENTIFICATION OF SOLID MATERIALS WITH A NEW ELECTROCHEMICAL TECHNIQUE - THE ABRASIVE STRIPPING ANALYSIS [J].

SCHOLZ, F ;

NITSCHKE, L ;

HENRION, G .

FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1989, 334 (01) :56-58

[10] A NEW PROCEDURE FOR FAST ELECTROCHEMICAL ANALYSIS OF SOLID MATERIALS [J].

SCHOLZ, F ;

NITSCHKE, L ;

HENRION, G .

NATURWISSENSCHAFTEN, 1989, 76 (02) :71-72