Catalytic hydrosilylation of alkenes by a ruthenium silylene complex. Evidence for new hydrosilylation mechanism

被引：214

作者：

Glaser, PB

Tilley, TD ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Ctr New Direct Organ Synth, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 45期

关键词：

D O I：

10.1021/ja037620v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel ruthenium and osmium silylene species containing Si?H bonds have been synthesized and characterized by NMR spectroscopy. The ruthenium complex [Cp*(iPr3P)(H)2Ru=Si(H)Ph·Et2O][B(C6F5)4] catalyzes the hydrosilyation of alkenes with excellent substrate selectivity for primary silanes and exclusive anti-Markovnikov regiochemistry. Evidence for a novel mechanism involving direct addition of an alkene to the silylene Si?H bond is presented. Copyright © 2003 American Chemical Society.

引用

页码：13640 / 13641

页数：2

共 37 条

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