95Mo NMR:: hyperfine interactions in MoO3, MoS2, MoSe2 Mo3Se4, MoSi2 and Mo2C

被引：21

作者：

Bastow, TJ ^{[1
]}

机构：

[1] CSIRO, Div Mat Sci & Technol, Clayton, Vic 3169, Australia

来源：

SOLID STATE NUCLEAR MAGNETIC RESONANCE | 1998年 / 12卷 / 04期

关键词：

Mo-95; NMR; hyperfine interactions; layer compounds; metals;

D O I：

10.1016/S0926-2040(98)00067-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nuclear hyperfine interactions have been obtained by nuclear magnetic resonance (NMR) for Mo-95 in a number of binary Mo compounds, both insulators and metals, which illustrate the interplay between nuclear quadrupole and chemical (Knight) shift terms. The insulating phases are characterised by nuclear spin lattice relaxation times greater than 100 s, demonstrating the ineffectiveness of indirect phonon Raman relaxation for these compounds. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：191 / 199

页数：9

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