endo/exo isomerism in norcarane and 2-norcaranol hydrotrioxides (ROOOH)

被引：12

作者：

Erzen, E ^{[1
]}

Cerkovnik, J ^{[1
]}

Plesnicar, B ^{[1
]}

机构：

[1] Univ Ljubljana, Fac Chem & Chem Technol, Dept Chem, Ljubljana 1000, Slovenia

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 23期

关键词：

D O I：

10.1021/jo035154m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ozonation of norcarane (1) yielded endo and exo norcarane hydrotrioxides (2a, 2b), as characterized by H-1 and C-13 NMR spectroscopy. Further ozonation of the primary decomposition products of these hydrotrioxides, i.e., 2-norcaranols (3), produced the corresponding isomeric 2-norcaranol hydrotrioxides (4a, 4b), and hydrogen trioxide (HOOOH).

引用

页码：9129 / 9131

页数：3

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