Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(II) and manganese(II)

被引:16
作者
Brewer, C
Brewer, G [1 ]
Butcher, RJ
Carpenter, EE
Cuenca, L
Schmiedekamp, AM
Viragh, C
机构
[1] Catholic Univ Amer, Washington, DC 20064 USA
[2] Howard Univ, Dept Chem, Washington, DC 20059 USA
[3] Virginia Commonwealth Univ, Dept Chem, Richmond, VA 23284 USA
[4] Penn State Univ, Abington Coll, Abington, PA 19001 USA
关键词
D O I
10.1039/b511566c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The iron(II) and manganese(II) complexes of the N-7 Schiff-base condensate of tris(3-aminopropyl)amine with 1-methyl-2-imidazolecarbaldehyde and the manganese(II) complex of the N7 Schiff- base condensate of tris(3-aminopropyl) amine with 4-imidazolecarbaldehyde are high-spin mono capped octahedral seven-coordinate complexes with a short, similar to 2.44 e, metal to apical nitrogen bond.
引用
收藏
页码:3617 / 3619
页数:3
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