Formation and properties of NO32-, NO3 and ONOO radicals in nitrate-containing matrices

被引:14
作者
Bannov, SI [1 ]
Nevostruev, VA [1 ]
机构
[1] Kemerovo State Univ, Dept Analyt Chem, Kemerovo 650043, Russia
关键词
symmetry; alkali nitrates; ground electronic states; radicals;
D O I
10.1016/S0969-806X(03)00013-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The analysis of both the EPR data, symmetry and the ground electronic states of radicals NO32-, NO3 and ONOO has been carried out. The influence of symmetry of the nitrate ion in various crystals on the formation of radicals, their stability and the parameters of their EPR spectra has been shown determined. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:917 / 924
页数:8
相关论文
共 25 条
[1]  
Atkins P. W., 1967, STRUCTURE INORGANIC
[2]  
Bannov SI, 1997, HIGH ENERG CHEM+, V31, P233
[3]  
Bannov SI, 1997, HIGH ENERG CHEM+, V31, P196
[4]  
BANNOV SI, 1992, KHIM VYS ENERG, V26, P324
[5]  
BANNOV SI, 1991, KHIM VYS ENERG, V25, P426
[6]   AN ABINITIO CHARACTERIZATION OF NITROGEN TRIOXIDE ELECTRONIC STATES [J].
BOEHM, RC ;
LOHR, LL .
JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (09) :3430-3433
[7]   THE STRUCTURE OF ND4NO3 PHASE-V BY NEUTRON POWDER DIFFRACTION [J].
CHOI, CS ;
PRASK, HJ .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1983, 39 (AUG) :414-420
[9]  
CUNNINGHAM J, 1968, RADICAL IONS, P475
[10]   DEPENDENCE OF TRANSITION PROPERTIES OF UNIVALENT NITRATES UPON STRUCTURAL ENTITIES [J].
FERMOR, JH ;
KJEKSHUS, A .
ACTA CHEMICA SCANDINAVICA, 1973, 27 (03) :915-923