A novel synthesis of thiono-ester S-oxides by substitution of chlorine in chlorosulfines

被引：7

作者：

Bonini, BF ^{[1
]}

Beulen, MWJ ^{[1
]}

ComesFranchini, M ^{[1
]}

Mazzanti, G ^{[1
]}

VandeVoort, HHJM ^{[1
]}

Zwanenburg, B ^{[1
]}

机构：

[1] UNIV NIJMEGEN,NSR CTR MOL STRUCT DESIGN & SYNTH,DEPT ORGAN CHEM,NL-6525 ED NIJMEGEN,NETHERLANDS

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1996年 / 108卷 / 1-4期

关键词：

chlorosulfines; nucleophilic displacement reactions; thiono-ester S-oxides; 1,3-dipolar cycloaddition reactions; thiadiazoline S-oxides;

D O I：

10.1080/10426509608029661

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thiono-ester S-oxides, a rather neglected class of sulfines, can be readily obtained by nucleophilic substitution of chlorine in chlorosulfines by sterically demanding phenolates and alcoholates. The reaction occurs with predominant retention of the configuration of the starting chlorosulfine.

引用

页码：289 / 293

页数：5

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