Oriented crystal growth model explains the formation of titania nanotubes

被引：162

作者：

Kukovecz, A

Hodos, N

Horváth, E

Radnóczi, G

Kónya, Z

Kiricsi, I

机构：

[1] Univ Szeged, Dept Appl & Environm Chem, H-6720 Szeged, Hungary

[2] Hungarian Acad Sci, Dept Struct Res, Inst Tech Phys, H-1051 Budapest, Hungary

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2005年 / 109卷 / 38期

关键词：

D O I：

10.1021/jp054320m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We discuss the formation mechanism of titania nanotubes synthesized by the hydrothermal method. On the basis of a comprehensive analysis of TEM, HRTEM, FT-Raman, and N-2 adsorption data, we point out some major shortcomings of the currently accepted trititanate sheet rollup mechanism. We suggest that a novel formation mechanism, oriented nanotube crystal growth from nanoloop seeds, can explain the experimental findings better than the ones proposed so far.

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页码：17781 / 17783

页数：3

相关论文

共 24 条

[1] CRYSTAL STRUCTURE OF NA2TI3O7 [J].

ANDERSSON, S ;

WADSLEY, AD .

ACTA CRYSTALLOGRAPHICA, 1961, 14 (12) :1245-&

[2]

Barbe CJ, 1997, J AM CERAM SOC, V80, P3157, DOI 10.1111/j.1151-2916.1997.tb03245.x

[3] The effect of hydrothermal conditions on the mesoporous structure of TiO2 nanotubes [J].

Bavykin, DV ;

Parmon, VN ;

Lapkin, AA ;

Walsh, FC .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (22) :3370-3377

[4] The structure of trititanate nanotubes [J].

Chen, Q ;

Du, GH ;

Zhang, S ;

Peng, LM .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 :587-593

[5] Nanocomposite polymer electrolytes for lithium batteries [J].

Croce, F ;

Appetecchi, GB ;

Persi, L ;

Scrosati, B .

NATURE, 1998, 394 (6692) :456-458

[6] Preparation and structure analysis of titanium oxide nanotubes [J].

Du, GH ;

Chen, Q ;

Che, RC ;

Yuan, ZY ;

Peng, LM .

APPLIED PHYSICS LETTERS, 2001, 79 (22) :3702-3704

[7] Photo sensitization of ion-exchangeable titanate nanotubes by CdS nanoparticles [J].

Hodos, M ;

Horváth, E ;

Haspel, H ;

Kukovecz, A ;

Kónya, Z ;

Kiricsi, I .

CHEMICAL PHYSICS LETTERS, 2004, 399 (4-6) :512-515

[8]

HODOS M, 2005, 19 WINT SCH EL PROP

[9] Formation of titanium oxide nanotube [J].

Kasuga, T ;

Hiramatsu, M ;

Hoson, A ;

Sekino, T ;

Niihara, K .

LANGMUIR, 1998, 14 (12) :3160-3163

[10] Lithium storage in nanostructured TiO2 made by hydrothermal growth [J].

Kavan, L ;

Kalbác, M ;

Zukalová, M ;

Exnar, I ;

Lorenzen, V ;

Nesper, R ;

Graetzel, M .

CHEMISTRY OF MATERIALS, 2004, 16 (03) :477-485