Hydrogen bonding in organometallic crystals .4. M-H center dot center dot center dot O hydrogen-boding interactions

被引：50

作者：

Braga, D ^{[1
]}

Grepioni, F ^{[1
]}

Tedesco, E ^{[1
]}

Biradha, K ^{[1
]}

Desiraju, GR ^{[1
]}

机构：

[1] UNIV HYDERABAD, SCH CHEM, HYDERABAD 500046, ANDHRA PRADESH, INDIA

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 12期

关键词：

D O I：

10.1021/om9600250

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

M-H...O hydrogen-bonding interactions in crystalline organometallic complexes and clusters of the transition metals have been investigated. Molecular and crystal structures determined by neutron and/of X-ray diffraction data have been retrieved from the Cambridge Structural Database. In a number of cases there is clear manifestation of M-H...O hydrogen bonding involving metal-bound H(''hydride''), atom(s) and oxygen atoms mainly belonging to CO groups. When the H-ligands are electronically suited to being hydrogen-bonding donors, the absence of M-H...O interactions is due to the steric congestion around the coordination sites of the H-ligands. Individual crystal structures have been examined in detail. It is suggested that the M-H...O hydrogen bond is an example of a soft intermolecular interaction and is comparable in strength to C-H...O hydrogen bonds.

引用

页码：2692 / 2699

页数：8

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