Mass spectral studies on the mechanism of thermal decomposition of Zn(NO3)2•nH2O

被引：37

作者：

Malecka, B

Gajerski, R

Malecki, A

Wierzbicka, M

Olszewski, P

机构：

[1] Stanislaw Staszic Univ Min & Met, Fac Mat Sci & Ceram, PL-30059 Krakow, Poland

[2] Polish Acad Sci, Inst Catalysis & Surface Chem, PL-30239 Krakow, Poland

来源：

THERMOCHIMICA ACTA | 2003年 / 404卷 / 1-2期

关键词：

zinc nitrate; thermal decomposition; QMS analysis;

D O I：

10.1016/S0040-6031(03)00101-1

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermal decomposition of Zn(NO3)(2)(.)nH(2)O(n = 4 and 6) was studied using TG,DTA and QMS techniques. Measurements were performed in helium and in dry air. It was found that the examined reaction is a multi-step process with overlapping stages. The whole process depends on the rate of heating. Degradation of nitrate(V) groups starts before all water of crystallisation is removed from the system. Zn(NO3)(2)(.)2Zn(OH)(2) was identified as intermediate product of decomposition of Zn(NO3)(2)(.)nH(2)O. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：125 / 132

页数：8

共 13 条

[1]

[Anonymous], 1994, WILEY REGISTRY MASS, V6th

[2]

BAILER JC, 1973, COMPREHENSIVE INORGA, P237

[3]

Feitknecht W., 1953, FORTSCHR CHEM FORSCH, V2, P670

[4] CRYSTAL STRUCTURES OF NITRATES OF DIVALENT HEXAQUOCATIONS .I. HEXAQUOZINC NITRATE [J].

FERRARI, A ;

BRAIBANT.A ;

LANFREDI, AM ;

TIRIPICC.A .

ACTA CRYSTALLOGRAPHICA, 1967, 22 :240-&

[5] Characterization of boron-incorporated zinc oxide film chemically prepared from an aqueous solution [J].

Izaki, M ;

Katayama, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (01) :210-213

[6] STRUCTURAL STUDY OF NICKEL AND ZINC HYDROXYNITRATES .1. STRUCTURAL CLASSIFICATION [J].

LOUER, M ;

LOUER, D ;

GRANDJEA.D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1973, B 29 (AUG15) :1696-1703

[7]

LOUER M, 1968, ACAD SCI PARIS, V266, P59

[8]

LOUER M, 1970, ACAD SCI PARIS, V270, P881

[9]

PANNETIER G, 1965, ACAD SCI PARIS, V261, P3146

[10] NEUTRON-DIFFRACTION STUDY OF MN(NO3)2.4H2O [J].

POPOV, D ;

HERAK, R ;

RADULOVIC, N ;

RIBAR, B .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1975, 142 (5-6) :347-355

← 1 2 →