In2Ge6O15(en)2:: A In-Ge compound composed of germanate layers linked by pillars of In2O6N4 double octahedra

被引：29

作者：

Pitzschke, D ^{[1
]}

Bensch, W ^{[1
]}

机构：

[1] Univ Kiel, Inst Anorgan Chem, D-24098 Kiel, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 36期

关键词：

crystal structure; germanium; hydrothermal synthesis; indium; thermochemistry;

D O I：

10.1002/anie.200351115

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two metals in one net: GeO4 tetrahedra and InO6N 2 octahedra are primary building units in a new indium germanate. The germanium layers (yellow) are linked by the InO6N2 units (red) to form a 3D network. The compound is prepared by a hydrothermal synthesis using GeO2 and In(OH)3 in an aqueous solution of ethylenediamine.

引用

页码：4389 / 4391

页数：3

共 30 条

[1]

ANTIPOV EV, 1990, KOORDINATS KHIM+, V16, P770

[2] Hydrothermal synthesis and structural characterization of a new organically templated germanate, Ge10O21(OH)•N4C6H21 [J].