Full color triboluminescence of rare-earth-doped hexacelsian (BaAl2Si2O8)

被引:45
作者
Ishihara, T
Tanaka, K [1 ]
Fujita, K
Hirao, K
Soga, N
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Sakyo Ku, Kyoto 6068501, Japan
[2] Hyogo Prefectural Inst Ind Res, Suma Ku, Kobe, Hyogo 6540037, Japan
关键词
insulators; optical properties; luminescence;
D O I
10.1016/S0038-1098(98)00271-3
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Luminescence induced by fracture has been observed in hexacelsian (BaAl2Si2O8) doped with Yb2+ or Ce3+. The color of luminescence varies depending on the kinds of doped rare-earth elements; Yb2+ and Ce3+ show green and blue luminescence, respectively. These materials, along with the hexacelsian doped with Sm2+ which exhibits triboluminescence with red color as reported by the present authors previously, realize full color triboluminescence. The triboluminescence spectra of these materials have been measured and compared with photoluminescence spectra. The triboluminescence spectra qualitatively agree with the photoluminescence spectra. It is inferred that the origin of the triboluminescence is the electronic transition of rare-earth ions excited by photons emitted due to fracture of hexacelsian. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:763 / 767
页数:5
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