Preparation of SAN/silicate nanocomposites using PMMA as a compatibilizer

被引:8
作者
Kim, KH
Jo, WH [1 ]
Jho, JY
Lee, MS
Lim, GT
机构
[1] Seoul Natl Univ, Hyperstruct Organ Mat Res Ctr, Seoul 151742, South Korea
[2] Seoul Natl Univ, Sch Mat Sci & Engn, Seoul 151742, South Korea
[3] Seoul Natl Univ, Sch Chem Engn, Seoul 151742, South Korea
[4] Chonnam Natl Univ, Fac Appl Chem, Kwangju 500757, South Korea
关键词
polymer/silicate nanocomposite; SAN; compatibilizer; exfoliated structure;
D O I
10.1007/BF02875454
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
Polymer/silicate nanocomposites were prepared via two-step manufacturing process: a master batch preparation and then mixing with matrix polymer. A hybrid of PMMA and Na-MMT with exfoliated structure was first prepared by emulsion polymerization of MMA in the presence of Na-MMT. For the case that SAN24, miscible with PMMA, is used as matrix, we could prepare a nanocomposite with exfoliated structure. However, SAN31 nanocomposite shows the aggregation and/or reordering of the silicate layers due to the immiscibility between SAN31 and PMMA.
引用
收藏
页码:97 / 101
页数:5
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