Effect of trivalent cation on the physicochemical properties of cobalt containing anionic clays

被引:39
作者
Kannan, S [1 ]
Swamy, CS [1 ]
机构
[1] INDIAN INST TECHNOL,DEPT CHEM,MADRAS 600036,TAMIL NADU,INDIA
关键词
D O I
10.1023/A:1018599211053
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A series of cobalt containing hydrotalcites having the general formula CoMCO(3)-HT where M = Al, Fe and Cr were synthesized by sequential and coprecipitation methods. The samples were primarily characterized by X-ray diffraction (XRD), infrared absorption studies, transmission electron microscopy-energy dispersive X-ray analysis (TEM-EDAX), thermogravimetry-differential scanning calorimetry (TG-DSC) and BET surface area measurements. The lattice parameters, FTIR stretching wavelengths for O-H bonds and thermal stability depended on the ionic radius of the trivalent M cation. Thermal calcination of these materials yielded a non-stoichiometric spinel-type phase whose crystallinity was also affected by the nature of the trivalent cation.
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页码:1623 / 1630
页数:8
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