An inorganic N-amino analogue of pyrrole: A five-membered ring with methylhydrazine and two B atoms as building blocks

被引：5

作者：

Engelhardt, U

Park, SS

机构：

[1] Inst. F. Anorganische Analyt. Chem., Freien Universität Berlin, D-14195 Berlin

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196010232

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound 1-methyl-4-methylamino-3,5-diphenyl-1,2,4-triaza-3,5-diborole, C14H18B2N4, has been synthesized from bis(dimethylamino)phenylborane and methylhydrazine. The molecular structure of the planar ring system is best described as an inorganic N-methylaminopyrrole with two rather short and two normal B-N bonds [1.40(1) and 1.44(1) Angstrom, mean] and a short N-N bond [1.414(5) Angstrom] in the ring [exocyclic N-N 1.441(4) Angstrom].

引用

页码：3248 / 3250

页数：3

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