Radical-type reactivity of the 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyl

被引：76

作者：

Amii, H

Vranicar, L

Gornitzka, H

Bourissou, D

Bertrand, G

机构：

[1] Univ Toulouse 3, CNRS, UMR 5069, Lab Heterochim Fondamentale & Appl, F-31062 Toulouse 04, France

[2] Univ Calif Riverside, Dept Chem, CNRS, UMR 2282,Joint Res Chem Lab, Riverside, CA 92521 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 05期

关键词：

D O I：

10.1021/ja039920i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Despite through-space and through-bond B-B interactions, the stable 1,3-bora-2,4-diphosphoniocyclobutane-1,3-diyl displays some radical-type behavior, as illustrated by the spontaneous formation of the trans 1,3-adduct with trimethyltin hydride and a B-spiro derivative with bromotrichloromethane. Copyright © 2004 American Chemical Society.

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页码：1344 / 1345

页数：2

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