Synthesis of novel CuS with hierarchical structures and its application in lithium-ion batteries

被引：144

作者：

Han, Yan ^{[1
,2
]}

Wang, Yaping ^{[1
]}

Gao, Wenhong ^{[1
]}

Wang, Yijing ^{[1
]}

Jiao, Lifang ^{[1
]}

Yuan, Huatang ^{[1
]}

Liu, Shuangxi ^{[2
]}

机构：

[1] Nankai Univ, Inst New Energy Mat Chem, Key Lab Adv Energy Mat Chem MOE, Tianjin 300071, Peoples R China

[2] Nankai Univ, Inst New Catalyt Mat Sci, Coll Chem, Tianjin 300071, Peoples R China

来源：

POWDER TECHNOLOGY | 2011年 / 212卷 / 01期

基金：

中国国家自然科学基金;

关键词：

CuS; Hierarchical structure; Solvothermal approach; Formation mechanism; Lithium-ion batteries; PHOTOCATALYTIC PROPERTIES; CATHODE MATERIAL; SULFIDE; ELECTROLYTE; FABRICATION; TRANSITION; NANOWIRES; ROUTE;

D O I：

10.1016/j.powtec.2011.04.028

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Novel sphere-like CuS hierarchical structures are fabricated by solvothermal approach without any surfactant and template. SEM and TEM characterizations show that the CuS sphere-like structures are composed of tens to hundreds of well-arranged and self-assembled nanoplates with a thickness of about 20 nm. The effects of dosage of CuCl2 center dot 6H(2)O, temperature and reaction time on the morphology of the products are systematically investigated and the results indicate that the CuS sphere-like hierarchical structures can only be obtained under certain experimental conditions. The possible formation mechanism of the CuS hierarchical structures is proposed. In addition, the possibility of using CuS as the electrode material for lithium ion batteries is studied. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：64 / 68

页数：5

共 32 条

[1] Synthesis and characterization of tubular CuS with flower-like wall from a low temperature hydrothermal route [J].

Chen, Lifei ;

Yu, Wei ;

Li, Yang .

POWDER TECHNOLOGY, 2009, 191 (1-2) :52-54

[2] A facile solution chemical route to self-assembly of CuS ball-flowers and their application as an efficient photocatalyst [J].

Cheng, Zhiguo ;

Wang, Shaozhen ;

Wang, Qian ;

Geng, Baoyou .

CRYSTENGCOMM, 2010, 12 (01) :144-149

[3] Electrochemical behaviors of CuS as a cathode material for lithium secondary batteries [J].

Chung, JS ;

Sohn, HJ .

JOURNAL OF POWER SOURCES, 2002, 108 (1-2) :226-231

[4] INSOLUBLE SULFIDE POSITIVE ELECTRODES FOR ORGANIC ELECTROLYTE LITHIUM SECONDARY BATTERIES [J].

DAMPIER, FW .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (12) :2501-2506

[5] Reactivity of transition metal (Co, Ni, Cu) sulphides versus lithium: The intriguing case of the copper sulphide [J].

Debart, A. ;

Dupont, L. ;

Patrice, R. ;

Tarascon, J. -M. .

SOLID STATE SCIENCES, 2006, 8 (06) :640-651

[6] Preparation of colloidal dispersion of CuS nanoparticles stabilized by SDS [J].

Dutta, A. ;

Dolui, S. K. .

MATERIALS CHEMISTRY AND PHYSICS, 2008, 112 (02) :448-452

[7] ELECTROCHEMICAL METHOD TO MEASURE COPPER IONIC DIFFUSIVITY IN A COPPER SULFIDE SCALE [J].

ETIENNE, A .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1970, 117 (07) :870-&

[8] COPPER(II) SULFIDE AS CATHODE ACTIVE MATERIAL IN SECONDARY LITHIUM BATTERIES [J].

EXNAR, I ;

HEP, J .

JOURNAL OF POWER SOURCES, 1993, 44 (1-3) :701-705

[9] Charge-discharge mechanism of mechanically alloyed NiS used as a cathode in rechargeable lithium batteries [J].

Han, SC ;

Kim, KW ;

Ahn, HJ ;

Ahn, JH ;

Lee, JY .

JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 361 (1-2) :247-251

[10] Nickel sulfide synthesized by ball milling as an attractive cathode material for rechargeable lithium batteries [J].

Han, SC ;

Kim, HS ;

Song, MS ;

Kim, JH ;

Ahn, HJ ;

Lee, JY .

JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 351 (1-2) :273-278

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