High regioselectivity in propylene hydroformylation using rhodium-bisphosphite catalysts is due to properties of the SRS diastereomer

被引:20
作者
Briggs, JR [1 ]
Whiteker, GT [1 ]
机构
[1] Dow Chem Co USA, Corp R&D, S Charleston, WV 25303 USA
关键词
D O I
10.1039/b105391b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The large cone angle and bite angle of the SRS ligand diastereomer in biphenol-based Rh-bisphosphite catalysts lead to high linear regioselectivity in the hydroformylation of propylene.
引用
收藏
页码:2174 / 2175
页数:2
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