Analysis of chord-length distributions

被引:26
作者
Burger, C
Ruland, W
机构
[1] Max Planck Inst Kolloid & Grenzflachenforsch, D-14424 Potsdam, Germany
[2] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
来源
ACTA CRYSTALLOGRAPHICA SECTION A | 2001年 / 57卷
关键词
D O I
10.1107/S0108767301005098
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A closed-form analytical solution for the inversion of the integral equation relating small-angle scattering intensity distributions of two-phase systems to chord-length distributions is presented. The result is generalized to arbitrary derivatives of higher order of the autocorrelation function and to arbitrary projections of the scattering intensity (including slit collimation). This inverse transformation offers an elegant way to investigate the impact of certain features, e.g. singularities, in the chord-length distribution or its higher-order derivatives on the scattering curve, e.g. oscillatory components in the asymptotic behavior at a large scattering vector. Several examples are discussed.
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页码:482 / 491
页数:10
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