The enthalpies of formation of lanthanide compounds I.: LnCl3 (cr), LnBr3 (cr) and LnI3 (cr)

被引：73

作者：

Cordfunke, EHP

Konings, RJM

机构：

[1] Commiss European Communities, Joint Res Ctr, Inst Transuranium Elements, D-76125 Karlsruhe, Germany

[2] Univ Amsterdam, Inst Mol Chem, NL-1018 WV Amsterdam, Netherlands

来源：

THERMOCHIMICA ACTA | 2001年 / 375卷 / 1-2期

关键词：

lanthanide trihalides; enthalpy of formation; critical evaluation;

D O I：

10.1016/S0040-6031(01)00509-3

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The enthalpies of formation of the lanthanide trichlorides, tribromides and tri-iodides have been evaluated from the experimental data available in literature. All experimental results have been re-calculated using a consistent set of the most recent auxiliary data. On the basis of the results obtained, recommended values are given in those cases where sufficient data are available. When this is not the case, the recommended values are obtained from estimations using empirical correlations based on the variation of the ionic radii or the atomic number, (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：17 / 50

页数：34

共 100 条

[1] ENTHALPIES OF FORMATION OF SM2O3(MONOCLINIC) AND SM2O3(CUBIC) [J].

BAKER, FB ;

LEWIS, EA ;

HANSEN, LD ;

PAVONE, D ;

HOLLEY, CE ;

FITZGIBB.GC .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1972, 4 (04) :621-&

[2] HIGH-PRESSURE POLYMORPHISM OF RARE-EARTH TRIHALIDES [J].

BECK, HP ;

GLADROW, E .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1979, 453 (06) :79-92

[3] THERMODYNAMICS OF LANTHANIDE ELEMENTS .3. MOLAR ENTHALPIES OF FORMATION OF TB-3+(AQ), HO-3+(AQ), YB-3+(AQ), YB-2+(AQ), TBBR3(CR), HOBR3(CR), AND YBBR3(CR) AT 298.15-K [J].

BETTONVILLE, S ;

GOUDIAKAS, J ;

FUGER, J .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1987, 19 (06) :595-604

[4] On the heat of formation of intermetallic alloys - Cerium alloys [J].

Biltz, W ;

Pieper, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1924, 134 (01) :13-24

[5] The heats of solution of rare earth metals [J].

Bommer, H ;

Hohmann, E .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1941, 248 (04) :357-372

[6] The heats of solution and formation of water-free chlorides of rare earth metals [J].

Bommer, H ;

Hohmann, E .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1941, 248 (04) :373-382

[7] LANTHANIDE THERMODYNAMIC PREDICTIONS [J].

BRATSCH, S ;

SILBER, HB .

POLYHEDRON, 1982, 1 (03) :219-223

[8] ENTHALPIES OF SOLUTION OF LANTHANIDE, YTTRIUM AND SCANDIUM TRIHALIDES IN WATER AND IN NON-AQUEOUS SOLVENTS [J].

BURGESS, J ;

KIJOWSKI, J .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1981, 43 (10) :2389-2392

[9]

BURNETT JL, 1964, UCRL11126 US AT EN C

[10]

BURNETT JL, 1964, UCRL11850

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