Selective oxidation of thioethers to sulfoxides with molecular oxygen mediated by rhodium(III)-dimethylsulfoxide complexes

被引：9

作者：

Srivastava, RS ^{[1
]}

机构：

[1] Univ Louisiana, Dept Chem, Lafayette, LA 70504 USA

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2001年 / 15卷 / 09期

关键词：

rhodium; catalysis; thioether; sulfoxide; oxidation;

D O I：

10.1002/aoc.222

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A rhodium-dimethylsulfoxide-promoted catalytic oxidation of a thioether to sulfoxide is studied. Screening of different rhodium complexes reveals moderate to excellent catalytic properties for the oxidation of thioethers using molecular oxygen as an oxidant. The scope of this reaction is discussed. Copyright (C) 2001 John Wiley & Sons, Ltd.

引用

收藏

页码：769 / 771

页数：3

相关论文

共 12 条

[1] A NEW LINKAGE ISOMER OF RHCL3(DMSO)(3) - PHOTOCHEMICAL-SYNTHESIS, CRYSTAL-STRUCTURE, AND REACTIVITY OF MER,TRANS-RHCL3(DMSO)(2)(DMSO) [J].

ALESSIO, E ;

FALESCHINI, P ;

SANTI, ASO ;

MESTRONI, G ;

CALLIGARIS, M .

INORGANIC CHEMISTRY, 1993, 32 (25) :5756-5761

[2] SULFUR-BONDED SULFOXIDE COMPLEXES OF RHODIUM(III) AND RHODIUM(I) [J].

JAMES, BR ;

MORRIS, RH .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1980, 58 (04) :399-408

[3] PROTONATED DIMETHYLSULFOXIDE, [ME2SO H OSME2]+ - NOVEL HYDROGEN-BRIDGED STRUCTURE - X-RAY CRYSTAL-STRUCTURE OF TRANS-[H(ME2SO)2][RHCL4(ME2SO)2] [J].

JAMES, BR ;

MORRIS, RH ;

EINSTEN, FWB ;

WILLIS, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (01) :31-32

[4] GEOMETRIC EFFECTS ON THE REDOX PROPERTIES OF COMPLEXES [RUX2(R2SO)N(R2S)4-N] AND THE IMPLICATIONS FOR OXIDATION CATALYSIS [J].

RILEY, D ;

LYON, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (01) :157-161

[5] SELECTIVE MOLECULAR-OXYGEN OXIDATION OF ALKYL SULFIDES TO SULFOXIDES CATALYZED BY DICHLOROTETRAKIS(DIMETHYL SULFOXIDE) RUTHENIUM(II) [J].

RILEY, DP .

INORGANIC CHEMISTRY, 1983, 22 (14) :1965-1967

[6] RUTHENIUM(II)-CATALYZED THIOETHER OXIDATION .3. SYNTHESES AND STRUCTURE OF MODEL COMPLEXES WITH THE NEW LINEAR TRIDENTATE LIGAND BIS(3-(ETHYLSULFINYL)PROPYL) SULFIDE [J].

RILEY, DP ;

OLIVER, JD .

INORGANIC CHEMISTRY, 1986, 25 (11) :1825-1830

[7] RUTHENIUM(II)-CATALYZED THIOETHER OXIDATION .1. SYNTHESIS OF MIXED SULFIDE AND SULFOXIDE COMPLEXES [J].

RILEY, DP ;

OLIVER, JD .

INORGANIC CHEMISTRY, 1986, 25 (11) :1814-1821

[8] RUTHENIUM(II)-CATALYZED THIOETHER OXIDATION .2. SYNTHESES AND CRYSTAL-STRUCTURES OF 2 RUTHENIUM(II) COMPLEXES WITH THE NEW LINEAR TRIDENTATE LIGAND 3-(ETHYLTHIO)-1-((3-(ETHYLTHIO)PROPYL)SULFINYL)PROPANE [J].

RILEY, DP ;

OLIVER, JD .

INORGANIC CHEMISTRY, 1986, 25 (11) :1821-1825

[9] MECHANISTIC STUDIES OF THE SELECTIVE OXYGEN OXIDATION OF SULFIDES TO SULFOXIDES CATALYZED BY DIHALORUTHENIUM(II) COMPLEXES [J].

RILEY, DP ;

SHUMATE, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (11) :3179-3184

[10] NOVEL RU(III) DIMETHYL-SULFOXIDE CATALYSTS FOR THE SELECTIVE OXIDATION OF THIOETHERS TO SULFOXIDES WITH MOLECULAR-OXYGEN [J].

SRIVASTAVA, RS ;

MILANI, B ;

ALESSIO, E ;

MESTRONI, G .

INORGANICA CHIMICA ACTA, 1992, 191 (01) :15-17