The progression of Al-based metal-organic frameworks - From academic research to industrial production and applications

被引：323

作者：

Gaab, Manuela ^{[1
]}

Trukhan, Natalia ^{[1
]}

Maurer, Stefan ^{[1
]}

Gummaraju, Raghu ^{[2
]}

Mueller, Ulrich ^{[1
]}

机构：

[1] BASF SE, Chem Res & Engn, D-67056 Ludwigshafen, Germany

[2] BASF Corp, Iselin, NJ 08830 USA

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2012年 / 157卷

关键词：

Aluminum; Metal-organic framework; MOF production; Large-scale application; ALUMINUM PYROMELLITATE; ADSORPTION; MIL-53; SIMULATIONS; FLEXIBILITY; TRANSITIONS; CHAINS;

D O I：

10.1016/j.micromeso.2011.08.016

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Al-based metal-organic frameworks (Al-MOFs) were first prepared and intensively studied by Ferey and co-workers. They synthesized and characterized various new structures (e.g. MIL-53, MIL-96, MIL-100, MIL-110). In parallel, BASF SE developed an own portfolio of MOFs. The synthesis for one of these Al-MOFs (Basolite A520) has recently been optimized to allow for organic solvent-free preparation. Basolite A520 can now be synthesized in a water-based route that has already led to ton-scale production. Thereby the Al-MOF is industrially produced via both an economic and environmentally compatible process. This reliable access together with their adsorption properties paves the way to the broad application of MOFs. The latter is driven by the current global megatrends that require innovative applications by high potential materials. (C) 2011 Elsevier Inc. All rights reserved.

引用

页码：131 / 136

页数：6

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