Electrolytic partial fluorination of organic compounds.: 30.: Drastic improvement of anodic monofluorination of 2-substituted 1,3-oxathiolan-5-ones using the novel fluorine source Et4NF•4HF

被引：44

作者：

Higashiya, S

Narizuka, S

Konno, A

Maeda, T

Momota, K

Fuchigami, T

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

[2] Morita Chem Ind Co Ltd, Dept Res & Dev, Yodogawa Ku, Osaka 5320002, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1999年 / 64卷 / 01期

关键词：

D O I：

10.1021/jo981437g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The highly regioselective anodic monofluorination of 2-substituted 1,3-oxathiolan-5-ones was successfully carried out using a novel supporting electrolyte, Et4NF . 4HF, while use of a conventional supporting electrolyte, Et3N . 3HF, resulted in no formation or extremely low yields of the fluorinated products.

引用

页码：133 / 137

页数：5

共 38 条

[1]

[Anonymous], 1991, Fluorine in Bioorganic Chemistry

[2] ELECTROCHEMICAL MONOFLUORINATION OF PYRIDINE - SYNTHESIS OF 2-FLUOROPYRIDINE AT A PLATINUM ANODE [J].