Chelating alkoxy-N-heterocyclic carbene complexes of silver and copper

被引：189

作者：

Arnold, PL ^{[1
]}

Scarisbrick, AC ^{[1
]}

Blake, AJ ^{[1
]}

Wilson, C ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 22期

关键词：

D O I：

10.1039/b107855k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Incorporation of an alkoxide functional group into an N-heterocyclic carbene (NHC) ligand allows the synthesis of the first anionic NHC chelating ligands, which react to give the first neutral, molecular silver(I) alkoxide carbene complex, and a copper(I) derivative containing the first non-macrocyclic, square planar Cu(I) centres.

引用

页码：2340 / 2341

页数：2

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