Transmetallations between aryltrialkyltins and borane:: synthesis of arylboronic acids and organotin hydrides

被引：14

作者：

Faraoni, MB ^{[1
]}

Koll, LC ^{[1
]}

Mandolesi, SD ^{[1
]}

Zúñiga, AE ^{[1
]}

Podestá, JC ^{[1
]}

机构：

[1] Univ Nacl Sur, Dept Quim & Ingn Quim, Inst Invest Quim Organ, RA-8000 Bahia Blanca, Argentina

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 613卷 / 02期

关键词：

transmetallations; aryltrialkyltins; borane; organotin hydrides; arylboronic acids;

D O I：

10.1016/S0022-328X(00)00536-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aryltrialkyltin compounds react with borane in THF to give mixtures of trialkyltin hydrides and arylboranes, which on hydrolysis give arylboronic acid in high yields. The arylboronic acids are easily separated and obtained free of organotins. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：236 / 238

页数：3

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