Ferrous wheels, ellipse [(tBu3SiS)FeX]n, and cube [(tBu3SiS)Fe(CCSitBu3)]4

被引:49
作者
Sydora, OL [1 ]
Wolczanski, PT [1 ]
Lobkovsky, EB [1 ]
机构
[1] Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA
关键词
cluster compounds; iron; magnetic properties; S ligands;
D O I
10.1002/anie.200351143
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The shapes of things to come: The use of the extremely bulky tBu3SiS ligand has enabled the synthesis of rare ferrous wheels (depicted), a unique ellipse, and an uncommon ferrous cube based on tetrahedral coordination. Fe=red, Cl=green, S=orange, Si=blue, C=gray.
引用
收藏
页码:2685 / 2687
页数:3
相关论文
共 45 条
[1]   Modulated magnetic coupling in alkoxoiron(III) rings by host-guest interactions with alkali metal cations [J].
Abbati, GL ;
Cornia, A ;
Fabretti, AC ;
Malavasi, W ;
Schenetti, L ;
Caneschi, A ;
Gatteschi, D .
INORGANIC CHEMISTRY, 1997, 36 (27) :6443-6446
[2]   A ferromagnetic ring of six manganese(III) ions with a S=12 ground state [J].
Abbati, GL ;
Cornia, A ;
Fabretti, AC ;
Caneschi, A ;
Gatteschi, D .
INORGANIC CHEMISTRY, 1998, 37 (07) :1430-+
[3]  
Benelli C, 1996, ANGEW CHEM INT EDIT, V35, P1825
[4]  
BENELLI C, 1996, ANGEW CHEM, V108, P1967
[5]   THE SYNTHESIS, STRUCTURE AND MAGNETIC-PROPERTIES OF A CYCLIC DODECANUCLEAR NICKEL-COMPLEX [J].
BLAKE, AJ ;
GRANT, CM ;
PARSONS, S ;
RAWSON, JM ;
WINPENNY, REP .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (20) :2363-2364
[6]   A CYCLIC HEXAIRON(III) COMPLEX WITH AN OCTAHEDRALLY COORDINATED SODIUM-ION AT THE CENTER, AN EXAMPLE OF THE [12]METALLACROWN-6 STRUCTURE TYPE [J].
CANESCHI, A ;
CORNIA, A ;
LIPPARD, SJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (04) :467-469
[7]  
Caneschi A, 1999, ANGEW CHEM INT EDIT, V38, P1295, DOI 10.1002/(SICI)1521-3773(19990503)38:9<1295::AID-ANIE1295>3.0.CO
[8]  
2-L
[9]  
Caneschi A., 1995, ANGEW CHEM, V107, P511
[10]  
Caneschi A, 1999, ANGEW CHEM, V111, P1372