Structural aspects of copper catalyzed atom transfer radical polymerization

被引：255

作者：

Pintauer, T ^{[1
]}

Matyjaszewski, K ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Ctr Macromol Engn, Dept Chem, Pittsburgh, PA 15213 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 11-12期

基金：

美国国家科学基金会; 美国安德鲁·梅隆基金会;

关键词：

atom transfer radical polymerization; copper(I); copper(II); structures;

D O I：

10.1016/j.ccr.2004.11.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Structural features of copper(I) and copper(II) complexes with bidentate, tridentate and tetradentate nitrogen based ligands commonly used in atom transfer radical polymerization (ATRP) were extensively reviewed and discussed based on several spectroscopic techniques. Complexing ligands included 2,2'-bipyridine (bpy), 4,4'-di(5-nonyl)-2,2'-bipyridine (dNbpy), NNM,APtetramethylethylenediamine (TMEDA), N-propyl(2-pyridyl)methanimine (NPrPMI), 2,2': 6,2" -terpyri dine (tpy), 4,4',4"-tris(5-nonyl)- 2,2':6',2"-terpyridine (tNtpy), N,N,N',N'',N'''-pentamethyldiethylenetriamine (PMDETA), N,N-bis(2-pyridylmethyl)octylamine (BPMOA), 1,1,4,7,10,10-hexamethyltriethylenetetramine (HMTETA), tris[2-(dimethylamino)ethyl]amine (Me6TREN), tris[(2-pyridyl)methyl]amine (TPMA) and 1,4,8,1 1-tetraaza-1,4,8,11-tetramethylcyclotetradecane (Me(4)CYCLAM). Additionally, structures of copper(I) and copper(II) complexes with diethylenetriamine (DETA), triethylenetetramine (TETA), N,N-bis(2-pyridylmethyl)amine (BPMA), tris[2-aminoethyl]amine (TREN) and 1,4,8,1 1-tetraazacyclotetradecane (CYCLAM) were discussed. The structures were found to depend on the complexing ligand, solvent and temperature. (c) 2004 Elsevier B.V. All rights reserved.

引用

页码：1155 / 1184

页数：30

共 324 条

[1] THE RELATIONSHIPS BETWEEN THE FORMATION-CONSTANTS OF 2,2'-BIPYRIDINE METAL(II) COMPLEXES AND THE DONOR NUMBERS OF SOLVENTS [J].

ABE, Y ;

WADA, G .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (05) :1936-1938

[2] THE FORMATION-CONSTANTS AND CONFIGURATIONS OF THE COMPLEXES OF CR(II), MN(II), FE(II), CO(II), CU(II), AND ZN(II) WITH 2,2'-BIPYRIDINE AND OF CO(II) WITH 2,2'-6',2''-TERPYRIDINE IN HEXAMETHYLPHOSPHORIC TRIAMIDE [J].

ABE, Y ;

WADA, G .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1981, 54 (11) :3334-3339

[3] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].

ADDISON, AW ;

RAO, TN ;

REEDIJK, J ;

VANRIJN, J ;

VERSCHOOR, GC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356

[4] A STABLE BIS(THIOLATE) OF COPPER(II) WITH LONG AXIAL COPPER SULFUR LINKAGES - CRYSTAL AND MOLECULAR-STRUCTURE OF TRANS-[CU(CYCLAM)(SC6F5)2] [J].

ADDISON, AW ;

SINN, E .

INORGANIC CHEMISTRY, 1983, 22 (08) :1225-1228

[5] SPECTROSCOPIC STUDIES ON COPPER(II) HALIDE-COMPLEXES WITH ISOMERIC BENZOYLPYRIDINES - ELECTRONIC AND ELECTRON-SPIN-RESONANCE SPECTRAL EVIDENCE FOR 5-COORDINATE COPPER(II) SPECIES IN SOLUTION [J].

AHUJA, IS ;

TRIPATHI, S .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1992, 48 (05) :759-764

[6] THERMAL AND COPPER-CATALYZED ADDITION OF SULFONYL BROMIDES TO PHENYLACETYLENE [J].

AMIEL, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (26) :3867-3870

[7] CRYSTAL AND MOLECULAR-STRUCTURE OF TRIS-(2,2'-BIPYRIDYL)COPPER(II) PERCHLORATE [J].

ANDERSON, OP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (23) :2597-2601

[8] CRYSTAL-STRUCTURES OF TETRAPHENYLARSONIUM DICHLOROCUPRATE(I), TETRAPHENYLPHOSPHONIUM DICHLOROCUPRATE(I) AND TETRAPHENYLPHOSPHONIUM DIBROMOCUPRATE(I) [J].

ANDERSSON, S ;

JAGNER, S .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1985, 39 (05) :297-305

[9] Design of initiators for living radical polymerization of methyl methacrylate mediated by ruthenium(II) complex [J].

Ando, T ;

Kamigaito, M ;

Sawamoto, M .

TETRAHEDRON, 1997, 53 (45) :15445-15457

[10] Iron(II) chloride complex for living radical polymerization of methyl methacrylate [J].

Ando, T ;

Kamigaito, M ;

Sawamoto, M .

MACROMOLECULES, 1997, 30 (16) :4507-4510

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