Subtle factors are important: radical formation and transmetallation in reactions of butyl cuprates with cyclohexyl iodide

被引：9

作者：

Bertz, SH ^{[1
]}

Human, J

Ogle, CA

Seagle, P

机构：

[1] Complex Study Ctr, Mendham, NJ 07945 USA

[2] Univ N Carolina, Charlotte, NC 28223 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2005年 / 3卷 / 03期

关键词：

D O I：

10.1039/b416612d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of Bu-2 CuLi.LiI and Bu2CuLi.LiCN with cyclohexyl iodide are critically dependent upon subtle factors such as the surface properties of the reaction vessel, nature of the solvent still and lot of 'ultrapure' copper salt in addition to major effects such as the Li counterion.

引用

页码：392 / 394

页数：3

共 29 条

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