The coordination of Ni2+ in aqueous solution at elevated temperature and pressure

被引：18

作者：

Howell, I ^{[1
]}

Neilson, GW ^{[1
]}

机构：

[1] UNIV BRISTOL,HH WILLS PHYS LAB,BRISTOL BS8 1TL,AVON,ENGLAND

来源：

JOURNAL OF CHEMICAL PHYSICS | 1996年 / 104卷 / 05期

关键词：

D O I：

10.1063/1.470960

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first order isotopic difference method of neutron diffraction was used to investigate the coordination of Ni2+ in a 1.2 m NiSO4 heavy water solution at 300 degrees C and 1 kbar. The results show that the ambient hydration structure is completely destroyed under these extreme conditions, and suggests that the structure is completely dominated by cation-anion interactions. (C) 1996 American Institute of Physics.

引用

页码：2036 / 2042

页数：7

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