Uranium-mediated activation of small molecules

被引:159
作者
Arnold, Polly L. [1 ]
机构
[1] Univ Edinburgh, EaStCHEM Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
关键词
H BOND ACTIVATION; SANDWICH COMPLEXES; CARBON-MONOXIDE; ELECTRONIC-STRUCTURE; CRYSTAL-STRUCTURE; TERMINAL ALKYNES; REACTIVITY; DINITROGEN; CHEMISTRY; COORDINATION;
D O I
10.1039/c1cc10834d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Molecular complexes of uranium are capable of activating a range of industrially and economically important small molecules such as CO, CO(2), and N(2); new and often unexpected reactions provide insight into an element that needs to be well-understood if future clean-energy solutions are to involve nuclear power.
引用
收藏
页码:9005 / 9010
页数:6
相关论文
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