Infrared study and isotopic effect of magnesium hydroxide

被引：50

作者：

de Oliveira, EF ^{[1
]}

Hase, Y ^{[1
]}

机构：

[1] Univ Estadual Campinas, Inst Quim, BR-13083970 Campinas, SP, Brazil

来源：

VIBRATIONAL SPECTROSCOPY | 2001年 / 25卷 / 01期

关键词：

IR spectroscopy; magnesium hydroxide; isotopic effect;

D O I：

10.1016/S0924-2031(00)00107-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The IR spectra of polycrystalline Mg(OH)(2) and ME(OD)(2) are reported in the 4000-40 cm(-1) region. Band assignments were discussed on the basis of isotopic band shifts of the fundamental vibrations by combining the results of factor group analysis for D-3d(3) crystal structure with the Teller-Redlich product rule for crystal vibrations. The band assignments proposed are different from the previous IR spectroscopic studies. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：53 / 56

页数：4

共 21 条

[1]

Aminoff G, 1921, Z KRISTALLOGR, V56, P506

[2] INFRARED SPECTRUM OF MG(OH)2 [J].

BENESI, HA .

JOURNAL OF CHEMICAL PHYSICS, 1959, 30 (03) :852-852

[3] The function of hydrogen in intermolecular forces [J].

Bernal, JD ;

Megaw, HD .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1935, 151 (A873) :0384-0420

[4] LATTICE VIBRATION SPECTRA OF MG(OH)2 AND CA(OH)2 [J].

BUCHANAN, RA ;

CASPERS, HH ;

MURPHY, J .

APPLIED OPTICS, 1963, 2 (11) :1147-1150

[5] Water of constitution and of crystallization. [J].

Coblentz, WW .

PHYSICAL REVIEW, 1905, 20 (04) :252-258

[6] POLARIZED INFRARED AND RAMAN-SPECTRA OF MG(OH)2 AND CA(OH)2 [J].

DAWSON, P ;

HADFIELD, CD ;

WILKINSON, GR .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1973, 34 (07) :1217-1225

[7] PROTON POSITIONS IN BRUCITE CRYSTALS [J].

ELLEMAN, DD ;

WILLIAMS, D .

JOURNAL OF CHEMICAL PHYSICS, 1956, 25 (04) :742-744

[8] RAMAN ACTIVE VIBRATIONAL-MODES AND ISOTOPIC EFFECTS OF 4 ISOTOPICALLY SUBSTITUTED LITHIUM HYDROXIDES [J].

HASE, Y ;

PAGOTTOYOSHIDA, IV .

CHEMICAL PHYSICS LETTERS, 1979, 65 (01) :46-49

[9] ISOTOPIC PRODUCT RULE FOR SOLID-STATE LITHIUM OXALATE [J].

HASE, Y .

SPECTROSCOPY LETTERS, 1987, 20 (01) :37-44

[10] ISOTOPIC PRODUCT RULE FOR SOLID-STATE LITHIUM-NITRATE [J].

HASE, Y .

MONATSHEFTE FUR CHEMIE, 1988, 119 (04) :425-427

← 1 2 3 →