Biorecovery of gold from jewellery wastes by Escherichia coli and biomanufacture of active Au-nanomaterial

被引：16

作者：

Deplanche, K. ^{[1
]}

Attard, G. A. ^{[2
]}

Macaskie, L. E. ^{[1
]}

机构：

[1] Univ Birmingham, Sch Biosci, Edgbaston Rd, Birmingham B15 2TT, W Midlands, England

[2] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, South Glam, Wales

来源：

BIOHYDROMETALLURY: FROM THE SINGLE CELL TO THE ENVIRONMENT | 2007年 / 20-21卷

基金：

英国生物技术与生命科学研究理事会;

关键词：

bioreduction; biorecovery; Escherichia coli; Desulfovibrio desulfuricans; gold; catalysis;

D O I：

10.4028/www.scientific.net/AMR.20-21.647

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

Microbial reduction of Au(III) from HAuCl4 was demonstrated. Escherichia coli and Desulfovibrio desulfuricans reduced I mM Au(III) in 60 and 120 min at pH 6.9 and 2.3 respectively. TEM and elemental analysis showed the formation of Au(0) nanoparticles and their pH-dependent cellular localisation. The concept was applied to the recovery of gold from jewellery waste leachates using E. coli. Bio-Au(0) nanoparticles were tested for catalytic activity in the oxidation of glycerol, achieving 30% conversion to glyceric acid. A simple bioprocess for conversion of waste to new material is suggested.

引用

页码：647 / +

页数：2

共 28 条

[1] Sulphate-reducing bacteria, palladium and the reductive dehalogenation of chlorinated aromatic compounds [J].

Baxter-Plant, V ;

Mikheenko, IP ;

Macaskie, LE .

BIODEGRADATION, 2003, 14 (02) :83-90

[2] SITES OF METAL-DEPOSITION IN THE CELL-WALL OF BACILLUS-SUBTILIS [J].

BEVERIDGE, TJ ;

MURRAY, RGE .

JOURNAL OF BACTERIOLOGY, 1980, 141 (02) :876-887

[3] Oxidation of glycerol using supported gold catalysts [J].

Carrettin, S ;

McMorn, P ;

Johnston, P ;

Griffin, K ;

Kiely, CJ ;

Attard, GA ;

Hutchings, GJ .

TOPICS IN CATALYSIS, 2004, 27 (1-4) :131-136

[4] Commercial aspects of gold applications: From materials science to chemical science [J].

Corti, CW ;

Holliday, RJ .

GOLD BULLETIN, 2004, 37 (1-2) :20-26

[5] Palladium and gold removal and recovery from precious metal solutions and electronic scrap leachates by Desulfovibrio desulfuricans [J].

Creamer, Neil J. ;

Baxter-Plant, Victoria S. ;

Henderson, John ;

Potter, M. ;

Macaskie, Lynne E. .

BIOTECHNOLOGY LETTERS, 2006, 28 (18) :1475-1484

[6]

CREAMER NJ, 2007, IN PRESS CATAL TODAY

[7] Formation and growth of Au nanoparticles inside live alfalfa plants [J].

Gardea-Torresdey, JL ;

Parsons, JG ;

Gomez, E ;

Peralta-Videa, J ;

Troiani, HE ;

Santiago, P ;

Yacaman, MJ .

NANO LETTERS, 2002, 2 (04) :397-401

[8] A simple one phase preparation of organically capped gold nanocrystals [J].

Green, M ;

O'Brien, P .

CHEMICAL COMMUNICATIONS, 2000, (03) :183-184

[9] INTERACTION OF GOLD(I) AND GOLD(III) COMPLEXES WITH ALGAL BIOMASS [J].

GREENE, B ;

HOSEA, M ;

MCPHERSON, R ;

HENZL, M ;

ALEXANDER, MD ;

DARNALL, DW .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1986, 20 (06) :627-632

[10] Continuous removal of Cr(VI) from aqueous solution catalysed by palladised biomass of Desulfovibrio vulgaris [J].

Humphries, AC ;

Nott, KP ;

Hall, LD ;

Macaskie, LE .

BIOTECHNOLOGY LETTERS, 2004, 26 (19) :1529-1532

← 1 2 3 →