Synthesis and self-assembly of porphyrin-linked fullerene on gold surface using S-Au linkage

被引：93

作者：

Akiyama, T ^{[1
]}

Imahori, H ^{[1
]}

Ajawakom, A ^{[1
]}

Sakata, Y ^{[1
]}

机构：

[1] OSAKA UNIV, INST SCI & IND RES, IBARAKI, OSAKA 567, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 10期

关键词：

D O I：

10.1246/cl.1996.907

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Porphyrin-linked fullerene bearing methylthio group was prepared by 1,3-dipolar cycloadditon of the azomethine ylide, generated in situ using N-methylglycine and a formylporphyrin, with C-60 Self-assembled monolayer was formed by soaking Au electrode into a solution of the porphyrin-C-60 dyad. The photocurrent was observed for the photochemical cell in the presence of electron carrier under illumination.

引用

页码：907 / 908

页数：2

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