Direct observation of a transition metal alkane complex, CpRe(CO)2(cyclopentane), using NMR spectroscopy

被引：177

作者：

Geftakis, S

Ball, GE ^{[1
]}

机构：

[1] Univ New S Wales, NMR Facil, Sydney, NSW 2052, Australia

[2] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1998年 / 120卷 / 38期

关键词：

D O I：

10.1021/ja981702f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：9953 / 9954

页数：2

共 16 条

[1] ACTIVATION OF THE C-H BONDS IN NEOPENTANE AND NEOPENTANE-D(12) BY (ETA(5)-C-5(CH3)(5))RH(CO)(2) - SPECTROSCOPIC AND TEMPORAL RESOLUTION OF RHODIUM-KRYPTON AND RHODIUM-ALKANE COMPLEX INTERMEDIATES [J].

BENGALI, AA ;

SCHULTZ, RH ;

MOORE, CB ;

BERGMAN, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (21) :9585-9589

[2] The mechanism of a C-H bond activation reaction in room-temperature alkane solution [J].

Bromberg, SE ;

Yang, H ;

Asplund, MC ;

Lian, T ;

McNamara, BK ;

Kotz, KT ;

Yeston, JS ;

Wilkens, M ;

Frei, H ;

Bergman, RG ;

Harris, CB .

SCIENCE, 1997, 278 (5336) :260-263

[3]

BROOKHART M, 1988, PROG INORG CHEM, V36, P1, DOI DOI 10.1002/9780470166376.CH1

[4] INTERACTION OF ALKANES WITH UNSATURATED METAL CENTERS .2. COMPLEXES OF ALKANES AND FLUOROALKANES WITH W(CO)5 IN THE GAS-PHASE [J].

BROWN, CE ;

ISHIKAWA, Y ;

HACKETT, PA ;

RAYNER, DM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (07) :2530-2536

[5]

CRABTREE RH, 1993, ANGEW CHEM INT EDIT, V32, P789, DOI 10.1002/anie.199307891

[6] TIME-RESOLVED IR CHARACTERIZATION OF CIS-[LW(CO)4(SOLVENT)] AND TRANS-[LW(CO)4(SOLVENT)][L=PPH3, P(O-I-PR)3, AND P(OET)3] IN NORMAL HEPTANE SOLUTION - THE SOLVENT AS A TOKEN LIGAND IN SHORT-LIVED REACTION INTERMEDIATES [J].

DOBSON, GR ;

HODGES, PM ;

HEALY, MA ;

POLIAKOFF, M ;

TURNER, JJ ;

FIRTH, S ;

ASALI, KJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (14) :4218-4224

[7] Transition metal alkane complexes [J].

Hall, C ;

Perutz, RN .

CHEMICAL REVIEWS, 1996, 96 (08) :3125-3146

[8] Substitution of eta(2)-dihydrogen by toluene and alkanes in IrXH(2)(H-2)(PPr3i)(2) complexes [J].

Lee, DW ;

Jensen, CM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (36) :8749-8750

[9] DIASTEREOMERIC AND ISOTOPIC SCRAMBLING IN (HYDRIDO)ALKYLIRIDIUM COMPLEXES - EVIDENCE FOR THE PRESENCE OF A COMMON ALKANE COMPLEX INTERMEDIATE [J].

MOBLEY, TA ;

SCHADE, C ;

BERGMAN, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (29) :7822-7823

[10] PHOTOCHEMISTRY OF GROUP VI HEXACARBONYLS IN LOW-TEMPERATURE MATRICES .2. INFRARED-SPECTRA AND STRUCTURES OF CO-13-ENRICHED HEXACARBONYLS AND PENTACARBONYLS OF CHROMIUM, MOLYBDENUM, AND TUNGSTEN [J].

PERUTZ, RN ;

TURNER, JJ .

INORGANIC CHEMISTRY, 1975, 14 (02) :262-270

← 1 2 →