A review of CO2 applications in the processing of polymers

被引:596
作者
Tomasko, DL [1 ]
Li, HB [1 ]
Liu, DH [1 ]
Han, XM [1 ]
Wingert, MJ [1 ]
Lee, LJ [1 ]
Koelling, KW [1 ]
机构
[1] Ohio State Univ, Dept Chem Engn, Columbus, OH 43210 USA
关键词
D O I
10.1021/ie030199z
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The use of supercritical carbon dioxide as a processing solvent for the physical processing of polymeric materials is reviewed. Fundamental properties of CO2/polymer systems are discussed with an emphasis on available data and measurement techniques, the development of theory or models for a particular property, and an evaluation of the current state of understanding for that property. Applications such as impregnation, particle formation, foaming, blending, and injection molding are described in detail including practical operating information for selected topics. The review concludes with some forward-looking discussion on the future Of CO2 in polymer processing.
引用
收藏
页码:6431 / 6456
页数:26
相关论文
共 337 条
[1]  
ABRAHAM FF, 1974, ADV THEORETICAL CH S, V1
[2]   A STUDY OF THE DYNAMICS OF FOAM GROWTH - ANALYSIS OF THE GROWTH OF CLOSELY SPACED SPHERICAL BUBBLES [J].
AMON, M ;
DENSON, CD .
POLYMER ENGINEERING AND SCIENCE, 1984, 24 (13) :1026-1034
[3]   A STUDY OF THE DYNAMICS OF FOAM GROWTH - SIMPLIFIED ANALYSIS AND EXPERIMENTAL RESULTS FOR BULK-DENSITY IN STRUCTURAL FOAM MOLDING [J].
AMON, M ;
DENSON, CD .
POLYMER ENGINEERING AND SCIENCE, 1986, 26 (03) :255-267
[4]   INTERFACIAL-TENSION OF IMMISCIBLE POLYMER BLENDS - TEMPERATURE AND MOLECULAR-WEIGHT DEPENDENCE [J].
ANASTASIADIS, SH ;
GANCARZ, I ;
KOBERSTEIN, JT .
MACROMOLECULES, 1988, 21 (10) :2980-2987
[5]  
[Anonymous], 2000, FOAM EXTRUSION PRINC
[6]  
[Anonymous], 1999, CHEM SYNTHESIS USING
[7]   Importance of phase equilibria for understanding supercritical fluid environments [J].
Arai, K ;
Adschiri, T .
FLUID PHASE EQUILIBRIA, 1999, 158 :673-684
[8]   Measurement and prediction of LDPE/CO2 solution viscosity [J].
Areerat, S ;
Nagata, T ;
Ohshima, M .
POLYMER ENGINEERING AND SCIENCE, 2002, 42 (11) :2234-2245
[9]  
AREERAT S, 2002, P PPS 18 POLYM PROC
[10]   DIFFUSION-INDUCED GROWTH OF A GAS BUBBLE IN A VISCOELASTIC FLUID [J].
AREFMANESH, A ;
ADVANI, SG .
RHEOLOGICA ACTA, 1991, 30 (03) :274-283