In-situ infrared thermographic analysis during dehydrogenation of cyclohexane over carbon-supported Pt catalysts using spray-pulsed reactor

被引:20
作者
Biniwale, RB
Yamashiro, H
Ichikawa, M [1 ]
机构
[1] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0010021, Japan
[2] Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan
[3] Natl Environm Engn Res Inst, Nagpur 440020, Maharashtra, India
基金
日本学术振兴会;
关键词
IR thermography; cyclohexane dehydrogenation; hydrogen production; Pt catalyst; spray-pulse injection;
D O I
10.1007/s10562-005-5198-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Infrared thermography, a tool used for screening of active catalytic materials generally during the exothermic reactions has been used for thermal imaging during strong endothermic reaction of dehydrogenation of cyclohexane on Pt catalyst supported on active carbon cloth ( CFF- 1500s) sheets. A spray- pulsed mode was used for injection of atomized cyclohexane and to create alternate wet and dry condition on catalyst surface. The simultaneous product gas analysis and recording of the temperature pro. le of the catalyst surface using an IR camera was carried out. The production rate of hydrogen via endothermic dehydrogenation reaction is greatly dependent on the temperature of the catalyst surface. The observed change in the temperature pro. le at wet and dry conditions with varying pulse- injection frequency and corresponding product gas analysis reveals that the spray- pulse mode is useful in improving the catalyst activity. Further the reaction conditions were optimized using thermal pro. le data.
引用
收藏
页码:23 / 31
页数:9
相关论文
共 25 条
[1]   EXCEEDING EQUILIBRIUM CONVERSION WITH A CATALYTIC MEMBRANE REACTOR FOR THE DEHYDROGENATION OF METHYLCYCLOHEXANE [J].
ALI, JK ;
NEWSON, EJ ;
RIPPIN, DWT .
CHEMICAL ENGINEERING SCIENCE, 1994, 49 (13) :2129-2134
[2]   Hydrogen production by reforming of iso-octane using spray-pulsed injection and effect of non-thermal plasma [J].
Biniwale, RB ;
Mizuno, A ;
Ichikawa, M .
APPLIED CATALYSIS A-GENERAL, 2004, 276 (1-2) :169-177
[3]   Thermal imaging of breathing patterns during CO oxidation on a Pd/glass cloth [J].
Digilov, R ;
Nekhamkina, O ;
Sheintuch, M .
AICHE JOURNAL, 2004, 50 (01) :163-172
[4]   SEASONAL STORAGE OF HYDROGEN IN LIQUID ORGANIC HYDRIDES - DESCRIPTION OF THE 2ND PROTOTYPE VEHICLE [J].
GRUNENFELDER, NF ;
SCHUCAN, TH .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1989, 14 (08) :579-586
[5]   Catalytic decalin dehydrogenation/naphthalene hydrogenation pair as a hydrogen source for fuel-cell vehicle [J].
Hodoshima, S ;
Arai, H ;
Takaiwa, S ;
Saito, Y .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2003, 28 (11) :1255-1262
[6]   Liquid-film-type catalytic decalin dehydrogeno-aromatization for long-term storage and long-distance transportation of hydrogen [J].
Hodoshima, S ;
Arai, H ;
Saito, Y .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2003, 28 (02) :197-204
[7]  
Holzwarth A, 1998, ANGEW CHEM INT EDIT, V37, P2644, DOI 10.1002/(SICI)1521-3773(19981016)37:19<2644::AID-ANIE2644>3.0.CO
[8]  
2-#
[9]   Efficient hydrogen production using cyclohexane and decalin by pulse-spray mode reactor with Pt catalysts [J].
Kariya, N ;
Fukuoka, A ;
Utagawa, T ;
Sakuramoto, M ;
Goto, Y ;
Ichikawa, M .
APPLIED CATALYSIS A-GENERAL, 2003, 247 (02) :247-259
[10]   Efficient evolution of hydrogen from liquid cycloalkanes over Pt-containing catalysts supported on active carbons under "wet-dry multiphase conditions" [J].
Kariya, N ;
Fukuoka, A ;
Ichikawa, M .
APPLIED CATALYSIS A-GENERAL, 2002, 233 (1-2) :91-102