Reversible cleavage of carbon-carbon bonds in benzonitrile using nickel(0)

被引：160

作者：

Garcia, JJ

Jones, WD ^{[1
]}

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

[2] Natl Autonomous Univ Mexico, Fac Quim, Mexico City 04510, DF, Mexico

[3] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 26期

关键词：

D O I：

10.1021/om0008474

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The nickel(0) fragment [(dippe)Ni] has been found to ct-coordinate to the CN bond of benzonitrile and undergo reversible insertion into the Ph-CN bond.

引用

页码：5544 / 5545

页数：2

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