[Mn(bipyridyl)(CO)3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction

被引：487

作者：

Bourrez, Marc ^{[1
]}

Molton, Florian ^{[1
]}

Chardon-Noblat, Sylvie ^{[1
]}

Deronzier, Alain ^{[1
]}

机构：

[1] Univ Grenoble 1, Lab Chim Inorgan Redox, Dept Chim Mol UMR 5250, Inst Chim Mol Grenoble FR CNRS 2607,CNRS, F-38041 Grenoble 09, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 42期

关键词：

carbon dioxide; carbonyl ligands; electrocatalysis; electrochemistry; manganese; ELECTROCHEMICAL REDUCTION; BONDED COMPLEXES; DIOXIDE; ELECTRON; PHOTOCHEMISTRY; CATALYSIS; ELECTROREDUCTION; CONVERSION; PATHWAYS; FILMS;

D O I：

10.1002/anie.201103616

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Manganese at work: Carbonyl bipyridyl complexes based on manganese, a non-noble abundant and inexpensive metal, have been proved to be excellent molecular catalysts for the selective electrochemical reduction of CO 2 to CO under mild conditions. Another advantage of manganese complexes over rhenium complexes is that these catalysts operate at markedly less overpotential (0.40 V gain). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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收藏

页码：9903 / 9906

页数：4

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