A highly active phosphine-free catalyst system for Heck reactions of aryl bromides

被引:147
作者
Reetz, MT [1 ]
Westermann, E [1 ]
Lohmer, R [1 ]
Lohmer, G [1 ]
机构
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
关键词
D O I
10.1016/S0040-4039(98)01967-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Palladium salts such as Pd(OAc)(2) or PdCl2(PhCN)(2) in the presence of N,N-dimethylglycine (DMG) constitute the simplest and one of the most reactive and selective catalyst systems for the Heck reaction of aryl bromides with olefins known to date. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:8449 / 8452
页数:4
相关论文
共 34 条
[1]   HETEROGENEOUS CATALYSIS IN ORGANIC-CHEMISTRY .10. EFFECT OF THE CATALYST SUPPORT ON THE REGIOCHEMISTRY OF THE HECK ARYLATION REACTION [J].
AUGUSTINE, RL ;
OLEARY, ST .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 95 (03) :277-285
[2]  
BELLER M, 1995, SYNLETT, P441
[3]   First palladium-catalyzed Heck reactions with efficient colloidal catalyst systems [J].
Beller, M ;
Fischer, H ;
Kuhlein, K ;
Reisinger, CP ;
Herrmann, WA .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 520 (1-2) :257-259
[4]  
Brase S, 1998, EUR J ORG CHEM, V1998, P671, DOI 10.1002/(SICI)1099-0690(199804)1998:4<671::AID-EJOC671>3.0.CO
[5]  
2-R
[6]  
Bumagin N.A., 1995, RUSS J ORG CHEM, V31, P439
[7]   RECENT DEVELOPMENTS AND NEW PERSPECTIVES IN THE HECK REACTION [J].
CABRI, W ;
CANDIANI, I .
ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (01) :2-7
[8]   PALLADIUM-CATALYZED BIS-COUPLING OF DIHALOAROMATICS WITH 2-AMIDOACRYLATES [J].
CARLSTROM, AS ;
FREJD, T .
JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (03) :1289-1293
[9]  
Cornils B., 1996, APPL HOMOGENEOUS CAT
[10]   FINE FEATHERS MAKE FINE BIRDS - THE HECK REACTION IN MODERN GARB [J].
DE MEIJERE, A ;
MEYER, FE .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (23-24) :2379-2411