Hybrid metal-polymer composites from functional block copolymers

被引:129
作者
Grubbs, RB [1 ]
机构
[1] Dartmouth Coll, Dept Chem, Hanover, NH 03755 USA
[2] Dartmouth Coll, Ctr Nanomat Res, Hanover, NH 03755 USA
关键词
block copolymers; metal-polymer complexes; nanocomposites; nanoparticles; self-organization;
D O I
10.1002/pola.20946
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The combination of metals and polymers in hybrid materials is a research area of great current interest. A number of methods for controlling the positioning of metallic species within polymer matrices on the nanometer scale have been developed. This highlight focuses on the use of functional block copolymers for the localization of metal species, especially nanoparticles, on the nanometer scale through block copolymer phase segregation. Research from the author's group on the use of alkyne-functional block copolymers for the preparation of cobalt-containing materials is discussed in this context. (c) 2005 Whiley Periodicals, Inc.
引用
收藏
页码:4323 / 4336
页数:14
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