Studies on the uptake behavior of a magnetic Co3O4-containing resin for Ni(II), Cu(II) and Hg(II) from their aqueous solutions

被引：62

作者：

Atia, AA ^{[1
]}

Donia, AM ^{[1
]}

Shahin, AE ^{[1
]}

机构：

[1] Menoufia Univ, Fac Sci, Dept Chem, Shibin Al Kawm, Egypt

来源：

SEPARATION AND PURIFICATION TECHNOLOGY | 2005年 / 46卷 / 03期

关键词：

heavy metals; chelating resins; metal oxides; adsorption; recovery;

D O I：

10.1016/j.seppur.2005.05.009

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A magnetic chelating resin was obtained from polymerization of glycidyl methacrylate in the presence of divinylbenzene as a crosslinker and finely divided magnetic particles of Co3O4. The resin obtained was investigated by means of XRD, IR, magnetic susceptibility and DTA/TGA thermal analysis. The measurements showed that the particles of Co3O4 became completely coated with a film of the resin. The embedded metal oxide particles impart magnetic properties to the resin in addition to increasing the chelating active sites on the surface. The resin obtained was modified with amine functionality and evaluated towards the uptake of Hg2+, Cu2+ and Ni2+ from their aqueous solutions. Various factors affecting the uptake behaviour such as contact time, pH and initial concentration of the metal ions were investigated. Uptake respectively. The adsorption results were found to fit Langmuir values of 2.10, 2.00 and 1.10 mmol/g were recorded for Hg2+, Cu2+ and Ni2+, model. The modified resin displays higher uptake capacity compared to the metal oxide-free resin. The loaded resin with metal ions was regenerated to efficiency of 97.5% using 1 M H2SO4. (C) 2005 Elsevier B.V. All rights reserved.

引用

页码：208 / 213

页数：6

共 18 条

[1] Adsorption behaviour of non-transition metal ions on a synthetic chelating resin bearing iminoacetate functions [J].

Atia, AA ;

Donia, AM ;

ELwakeel, KZ .

SEPARATION AND PURIFICATION TECHNOLOGY, 2005, 43 (01) :43-48

[2] Studies on uptake behaviour of copper(II) and lead(II) by arnine chelating resins with different textural properties [J].

Atia, AA ;

Donia, AM ;

Abou-El-Enein, SA ;

Yousif, AM .

SEPARATION AND PURIFICATION TECHNOLOGY, 2003, 33 (03) :295-301

[3] Synthesis of amine and thio chelating resins and study of their interaction with zinc(II), cadmium(II) and mercury(II) ions in their aqueous solutions [J].

Atia, AA ;

Donia, AM ;

Yousif, AM .

REACTIVE & FUNCTIONAL POLYMERS, 2003, 56 (01) :75-82

[4] Polymer supported inorganic nanoparticles: characterization and environmental applications [J].

Cumbal, L ;

Greenleaf, J ;

Leun, D ;

SenGupta, AK .

REACTIVE & FUNCTIONAL POLYMERS, 2003, 54 (1-3) :167-180

[5]

De SantaMaria L.C., 2003, EUR POLYM J, V39, P843

[6] Mercury removal from synthetic solutions using poly (2-hydroxyethylmethacrylate) gel beads modified with poly (ethyleneimine) [J].

Denizli, A ;

Senel, S ;

Alsancak, G ;

Tüzmen, N ;

Say, R .

REACTIVE & FUNCTIONAL POLYMERS, 2003, 55 (02) :121-130

[7] Gold(III) recovery using synthetic chelating resins with amine, thio and amine/mercaptan functionalities [J].

Donia, AM ;

Atia, AA ;

Elwakeel, KZ .

SEPARATION AND PURIFICATION TECHNOLOGY, 2005, 42 (02) :111-116

[8]

DONIA AM, 2005, IN PRESS J SEP PURIF

[9] Chemical modification of chitosan and equilibrium study for mercury ion removal [J].

Jeon, C ;

Höll, WH .

WATER RESEARCH, 2003, 37 (19) :4770-4780

[10]

Kagel R. O., 1971, INFRARED SPECTRA INO

← 1 2 →