Harnessing thorium(IV) as a catalyst: RNA and phosphate diester cleavage by a thorium(IV) macrocyclic complex

被引：20

作者：

Wang, CF ^{[1
]}

Choudhary, S ^{[1
]}

Vink, CB ^{[1
]}

Secord, EA ^{[1
]}

Morrow, JR ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Amherst, NY 14260 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 24期

关键词：

D O I：

10.1039/b005866l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A robust macrocyclic tetraamide complex of Th(iv) binds phosphate diesters and promotes cleavage of RNA and phosphate diesters at 37 degreesC in the pH range 5.00-7.90.

引用

页码：2509 / 2510

页数：2

共 18 条

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