'CMPO-substituted' calix[4]arenes, extractants with selectivity among trivalent lanthanides and between trivalent actinides and lanthanides

被引：90

作者：

Delmau, LH

Simon, N

Schwing-Weill, MJ

Arnaud-Neu, F

Dozol, JF

Eymard, S

Tournois, B

Böhmer, V

Grüttner, C

Musigmann, C

Tunayar, A

机构：

[1] CEN Cadarache, DESD, SEP, LPTE, F-13108 St Paul Durance, France

[2] ECPM, F-67008 Strasbourg, France

[3] Johannes Gutenberg Univ, Inst Organ Chem, D-55099 Mainz, Germany

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 16期

关键词：

D O I：

10.1039/a802555j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Calix[4]arenes substituted by acetamidophosphine oxide groups at their wider (upper) rim not only exhibit excellent extraction efficiency towards trivalent cations but also show pronounced selectivity for the light lanthanides and actinides in their extraction from highly saline or acidic media.

引用

收藏

页码：1627 / 1628

页数：2

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