Lead-promoted 2-carboethoxyallylation or 2-carboxylallylation of aldehydes: A new and facile method for the synthesis of alpha-methylene-gamma-butyrolactones

被引：8

作者：

Zhou, JY ^{[1
]}

Jia, Y ^{[1
]}

Yao, XB ^{[1
]}

Wu, SH ^{[1
]}

机构：

[1] FUDAN UNIV,DEPT CHEM,SHANGHAI 200433,PEOPLES R CHINA

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 12期

关键词：

D O I：

10.1080/00397919608004550

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of powdered lead, the reaction of aldehydes and alpha-bromomethylacrylate (or alpha-bromomethylacrylic acid) can be carried out under mild condition, the products 4-hydroxy-2-methylenebutanoates (or 4-hydroxy-2-methylenebutanoic acids) can be easily converted to alpha- methylene-gamma-butyrolactones in the presence of CF3COOH.

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页码：2397 / 2406

页数：10

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