A molybdenum V diphosphate with the KMoOP2O7 structure: NaMoOP2O7

被引：16

作者：

Ledain, S

Leclaire, A

Borel, MM

Provost, J

Raveau, B

机构：

[1] Laboratoire CRISMAT, URA 1318 Associe au CNRS-ISMRA, Université de Caen, 14050 Caen Cedex, Blvd. du Marechal Juin

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1996年 / 124卷 / 01期

关键词：

D O I：

10.1006/jssc.1996.0202

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new molybdenum (V) diphosphate, NaMoOP2O7, with the KMoOP2O7 structure has been synthesized. This phase differs from KMoOP2O7 by its P2(1)2(1)2(1) space group (a = 11.387 Angstrom, b = 5.146 Angstrom, c = 10.070 Angstrom). In comparison to KMoOP2O7, the MoO6 octahedra of NaMoOP2O7 are dramatically distorted, and the P2O7 groups exhibit a staggered configuration with a different distribution of the P-O distances. (C) 1996 Academic Press, Inc.

引用

页码：24 / 28

页数：5

共 9 条

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