Electrorheological characteristics of semiconducting poly(aniline-co-o-ethoxyaniline) suspension

被引:76
作者
Choi, HJ [1 ]
Kim, JW
To, KW
机构
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
[2] Acad Sinica, Inst Phys, Taipei 11529, Taiwan
关键词
poly(aniline-co-o-ethoxyaniline); polyaniline; electrorheological (ER) fluids;
D O I
10.1016/S0032-3861(98)00418-2
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Semiconducting poly(aniline-co-o-ethoxyaniline) was synthesized by chemical oxidation polymerization of aniline and o-ethoxyaniline with two different molar ratios in an acidic media. Its chemical structure and other physical propel-ties, such as conductivity, thermal stability and density of the polymer particles, were examined. Electrorheological (ER) fluids were then prepared by dispersing the copolyaniline particles in silicone oil and their rheological properties under electric field were investigated. It was found that the ER fluids using copolyanilines show different ER behaviors than that of the homopolyaniline. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2163 / 2166
页数:4
相关论文
共 19 条
[1]   MATERIALS AND MECHANISMS IN ELECTRORHEOLOGY [J].
BLOCK, H ;
KELLY, JP ;
QIN, A ;
WATSON, T .
LANGMUIR, 1990, 6 (01) :6-14
[2]   Effect of ionic pendent groups on a polyaniline-based electrorheological fluid [J].
Cho, MS ;
Choi, HJ ;
To, KW .
MACROMOLECULAR RAPID COMMUNICATIONS, 1998, 19 (06) :271-273
[3]   N-substituted copolyaniline for electrorheological material [J].
Cho, MS ;
Kim, TW ;
Choi, HJ ;
Jhon, MS .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1997, 16 (08) :672-673
[4]  
Choi HJ, 1997, POLYM ADVAN TECHNOL, V8, P697, DOI 10.1002/(SICI)1099-1581(199711)8:11<697::AID-PAT703>3.0.CO
[5]  
2-X
[6]   Electrorheological characterization of polyaniline dispersions [J].
Choi, HJ ;
Kim, TW ;
Cho, MS ;
Kim, SG ;
Jhon, MS .
EUROPEAN POLYMER JOURNAL, 1997, 33 (05) :699-703
[7]   Electrorheological and dielectric characteristics of semiconductive polyaniline-silicone oil suspensions [J].
Choi, HJ ;
Cho, MS ;
To, K .
PHYSICA A, 1998, 254 (1-2) :272-279
[8]  
Coulter J.P., 1993, J INTEL MAT SYST STR, V4, P248
[9]   A NOVEL N-SUBSTITUTED POLYANILINE DERIVATIVE [J].
DEARMITT, C ;
ARMES, SP ;
WINTER, J ;
URIBE, FA ;
GOTTESFELD, S ;
MOMBOURQUETTE, C .
POLYMER, 1993, 34 (01) :158-162
[10]   INSULATOR-TO-METAL TRANSITION IN POLYANILINE [J].
EPSTEIN, AJ ;
GINDER, JM ;
ZUO, F ;
BIGELOW, RW ;
WOO, HS ;
TANNER, DB ;
RICHTER, AF ;
HUANG, WS ;
MACDIARMID, AG .
SYNTHETIC METALS, 1987, 18 (1-3) :303-309