Electrochemical investigations in supercritical carbon dioxide

被引：51

作者：

Abbott, AP

Harper, JC

机构：

[1] Chemistry Department, Leicester University, Leicester

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1996年 / 92卷 / 20期

关键词：

D O I：

10.1039/ft9969203895

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It has been shown that hydrophobic electrolytes can be dissolved in supercritical carbon dioxide (scCO(2)) to give conducting media. The conductivity is comparable with that of similar electrolytes in cyclohexane under ambient conditions. The solubility of the electrolyte in supercritical media is related to the density of the medium. Electron-transfer processes are demonstrated for the first time in both cyclohexane and unmodified scCO(2) at a macroscopic electrode.

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页码：3895 / 3898

页数：4

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